A Co(ii)-catalyzed asymmetric ring opening reaction of spiro-epoxyoxindoles with allylboron-Reference-Cited by-同舟云学术

A Co(ii)-catalyzed asymmetric ring opening reaction of spiro-epoxyoxindoles with allylboron

Published:2020 Issue:6 Volume:7 Page:862-867
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wu Liang¹²³⁴⁵,Shao Qihang¹²³⁴⁵,Kong Li⁶³⁴⁵,Chen Jianzhong¹²³⁴⁵,Wei Quhao⁶³⁴⁵,Zhang Wanbin¹²³⁴⁵^ORCID

Affiliation:

1. Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs

2. School of Chemistry and Chemical Engineering

3. Shanghai Jiao Tong University

4. Shanghai 200240

5. P. R. China

6. 6th People's Hospital South Campus

Abstract

A Co(ii)/BOX-catalyzed asymmetric allylation of spiroepoxyoxindoles was developed, which is the first stereoconvergent allylation of epoxides, yielding chiral oxindoles bearing quaternary stereocenters.

Funder

National Natural Science Foundation of China

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00072H

Reference66 articles.

1. Asymmetric Catalysis of Epoxide Ring-Opening Reactions

2. Aziridines and Epoxides in Organic Synthesis , ed. A. K. Yudin , Wiley-VCH , Weinheim , 2006

3. Epihalohydrins in Organic Synthesis

4. The Chemistry of Transition Metals with Three-Membered Ring Heterocycles

5. Organocatalytic Asymmetric Reactions of Epoxides: Recent Progress

Cited by 22 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Metal-Catalyzed Enantioconvergent Transformations;Chemical Reviews;2023-10-04

2. Quaternary Stereocenters via Catalytic Enantioconvergent Allylation of Epoxides;Journal of the American Chemical Society;2023-09-18

3. Chemical Modification of Peptides and Proteins Using Spirooxindole Oxirane Derivatives;Advanced Synthesis & Catalysis;2023-06-29

4. Synthesis, Characterization, and Catalytic Reactivities of Novel Dinuclear Cu(II) Complexes : Efficient Ring Opening Reaction of Epoxide;ChemistrySelect;2023-04-24

5. Solvent‐free Darzens condensation of 3‐ chlorooxindoles with aryl aldehydes for diastereoselective construction of spiro‐epoxyoxindoles by grinding;Journal of Heterocyclic Chemistry;2022-12-21