Dielectric phase transition of an A2BX4-type perovskite with a pentahedral to octahedral transformation

Author:

Chai Siqian1234,Xiong Jianbo5634,Zheng Yongshen5634,Shi Rongchao5634,Xu Jialiang12345ORCID

Affiliation:

1. School of Chemical Engineering and Technology

2. Tianjin University

3. Tianjin 300350

4. China

5. School of Materials Science and Engineering

6. Nankai University

Abstract

The as-synthesized 2D perovskite [C5H12N]2PbCl4 undergoes an above-room-temperature dielectric phase transition with a reversible pentahedral to octahedron transformation and a high dielectric constant being over twice of the low dielectric constant.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Nankai University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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