Ni single atoms on carbon nitride for visible-light-promoted full heterogeneous dual catalysis

Author:

Kwak Minjoon1,Bok Jinsol12ORCID,Lee Byoung-Hoon12ORCID,Kim Jongchan1,Seo Youngran1,Kim Sumin1,Choi Hyunwoo1,Ko Wonjae12,Hooch Antink Wytse12,Lee Chan Woo12,Yim Guk Hee1,Seung Hyojin12,Park Chansul12,Lee Kug-Seung3ORCID,Kim Dae-Hyeong12ORCID,Hyeon Taeghwan12ORCID,Yoo Dongwon12ORCID

Affiliation:

1. Department of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Seoul 08826, Republic of Korea

2. Center for Nanoparticle Research, Institute for Basic Science (IBS), Seoul 08826, Republic of Korea

3. Pohang Accelerator Laboratory (PAL), Pohang University of Science and Technology (POSTECH), Pohang, Gyeongbuk 37673, Republic of Korea

Abstract

In this work, the first demonstration of heterogeneous photoredox C–N coupling is reported using Ni atoms on C3N4. Due to metal–support interactions, high activity and stability were observed during visible-light-driven C–N functionalization.

Funder

Institute for Basic Science

National Research Foundation of Korea

Seoul National University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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