Importance of polarization assisted/resonance assisted hydrogen bonding interactions and unconventional interactions in crystal formations of five new complexes bearing chelidamic acid through a proton transfer mechanism

Author:

Mirzaei Masoud1234,Eshtiagh-Hosseini Hossein1234,Shamsipur Mojtaba1564,Saeedi Mahdi1234,Ardalani Mehdi1564,Bauzá Antonio78910,Mague Joel T.1111213,Frontera Antonio78910,Habibi Morteza15641

Affiliation:

1. Department of Chemistry

2. Ferdowsi University of Mashhad

3. Mashhad 917751436

4. Iran

5. Razi University

6. Kermanshah

7. Departament de Química

8. Universitat de les Illes Balears

9. 07122 Palma de Mallorca (Baleares)

10. Spain

11. Tulane University

12. New Orleans

13. USA

Abstract

Five new coordination compounds derived from chelidamic acid and amines have been synthesized and X-ray characterized. The noncovalent interactions that govern the crystal packing have been rationalized by means of DFT calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference48 articles.

1. The Hydrogen Bond in the Solid State

2. Resonance-assisted hydrogen bonds revisited. Resonance stabilization vs. charge delocalization

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4. What Is the Covalency of Hydrogen Bonding?

5. Hydrogen Bonding – New Insights, in Series Challenges and Advances in Computational Chemistry and Physics, ed. S. J. Grabowski and J. Leszczynski, Springer, New York, 2006

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