Exploring the origin of the anomeric relationships in 2-cyanooxane, 2-cyanothiane, 2-cyanoselenane and their corresponding isocyano isomers. Correlations between hyper-conjugative anomeric effect, hardness and electrostatic interactions
Author:
Affiliation:
1. Department of Chemistry
2. College of Science
3. Arak Branch
4. Islamic Azad University
5. Arak
Abstract
The impacts of the HCAE, hardness, PETR and electrostatic interactions on the anomeric relationships in 2-cyanooxane, -thiane, -selenane and their iso-cyano isomers have been explored.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA06080C
Reference54 articles.
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4. Anomeric and reverse anomeric effects in the gas phase and aqueous solution
5. Exo-anomeric effects on energies and geometries of different conformations of glucose and related systems in the gas phase and aqueous solution
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