Synthesis and photoinitiated thiol–ene reactions of exo-mannals – a new route to C-β-d-mannosyl derivatives-Reference-Cited by-同舟云学术

Synthesis and photoinitiated thiol–ene reactions of exo-mannals – a new route to C-β-d-mannosyl derivatives

Published:2020 Issue:57 Volume:10 Page:34825-34836
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

József János¹²³⁴²,Debreczeni Nóra⁵²³⁴²,Eszenyi Dániel⁵²³⁴,Borbás Anikó⁵²³⁴^ORCID,Juhász László¹²³⁴^ORCID,Somsák László¹²³⁴^ORCID

Affiliation:

1. Department of Organic Chemistry

2. University of Debrecen

3. H-4002 Debrecen

4. Hungary

5. Department of Pharmaceutical Chemistry

Abstract

A synthetic procedure was elaborated for O-peracylated exo-mannals. Thiol-ene additions to pyranoid and furanoid exo-mannals gave mannosylmethyl sulfide type adducts with exclusive regio- and β(d)-stereoselectivities including disaccharide mimetics.

Funder

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA07115C

Reference46 articles.

1. Mannose metabolism: More than meets the eye

2. Protein O-mannosylation: What we have learned from baker's yeast

3. Protein C-Mannosylation and Its Prospective Functions in the Cell

4. Emerging roles of protein mannosylation in inflammation and infection

5. d-mannose powder for prophylaxis of recurrent urinary tract infections in women: a randomized clinical trial

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