Disorder in Ho2Ti2−xZrxO7: pyrochlore to defect fluorite solid solution series-Reference-Cited by-同舟云学术

Disorder in Ho2Ti2−xZrxO7: pyrochlore to defect fluorite solid solution series

Published:2020 Issue:57 Volume:10 Page:34632-34650
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Drey Devon L.¹²³⁴^ORCID,O'Quinn Eric C.¹²³⁴,Subramani Tamilarasan⁵⁶⁷⁸⁴,Lilova Kristina⁵⁶⁷⁸⁴,Baldinozzi Gianguido⁹¹⁰¹¹¹²¹³,Gussev Igor M.¹²³⁴,Fuentes Antonio F.¹⁴¹⁵¹⁶^ORCID,Neuefeind Joerg C.¹⁷¹⁸¹⁹⁴,Everett Michelle¹⁷¹⁸¹⁹⁴,Sprouster David²⁰²¹²²⁴^ORCID,Navrotsky Alexandra⁵⁶⁷⁸⁴,Ewing Rodney C.²³²⁴²⁵⁴,Lang Maik¹²³⁴

Affiliation:

1. Department of Nuclear Engineering

2. University of Tennessee

3. Knoxville

4. USA

5. School of Molecular Sciences

6. Center for Materials of the Universe

7. Arizona State University

8. Tempe

9. Laboratoire Structures, Propriétés et Modélisation des Solides

10. CNRS

11. Centrale Supélec

12. Université Paris-Saclay

13. F-91190 Gif-sur-Yvette

14. Cinvestav Unidad Saltillo

15. 25900 Ramos Arizpe

16. Mexico

17. Neutron Scattering Division

18. Oak Ridge National Laboratory

19. Oak Ridge

20. Department of Materials Science and Chemical Engineering

21. State University of New York

22. Stony Brook

23. Department of Geological Sciences

24. Stanford University

25. Stanford

Abstract

Combined neutron and X-ray total scattering with calorimetric measurements of the solid solution series Ho₂Ti_2−xZr_xO₇ reveals a complex order–disorder transition across short, intermediate, and long length scales induced by chemical substitution.

Funder

U.S. Department of Energy

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA07118H

Reference93 articles.

1. Oxide pyrochlores — A review

2. Nuclear waste disposal—pyrochlore (A2B2O7): Nuclear waste form for the immobilization of plutonium and “minor” actinides