Ligand design and nuclearity variation towards dual emissive Pt(ii) complexes for singlet oxygen generation, dual channel bioimaging, and theranostics

Author:

Shafikov Marsel Z.12ORCID,Suleymanova Alfiya F.3ORCID,Kutta Roger J.1ORCID,Gorski Alexander4ORCID,Kowalczyk Aleksandra5ORCID,Gapińska Magdalena6ORCID,Kowalski Konrad7ORCID,Czerwieniec Rafał1ORCID

Affiliation:

1. Institut für Physikalische und Theoretische Chemie, Universität Regensburg, Universitätsstrasse 31, Regensburg, D-93053, Germany

2. Ural Federal University, Mira 19, Ekaterinburg, 620002, Russia

3. Chemistry Department, University of York, Heslington, York, YO10 5DD, UK

4. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw, Poland

5. Department of Molecular Microbiology, Faculty of Biology and Environmental Protection, University of Łódź, Banacha 12/16, 90-237, Łódź, Poland

6. Laboratory of Microscopic Imaging and Specialized Biological Techniques, Faculty of Biology and Environmental Protection, University of Łódź, Banacha 12/16, 90-237, Łódź, Poland

7. Faculty of Chemistry, Department of Organic Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, Poland

Abstract

Mono- and dinuclear Pt(ii) complexes of a new ditopic ligand with a thiophene cyclometalating core are reported. The mononuclear complex shows dual emission of fluorescence and phosphorescence and is demonstrated as a dual channel bioimaging probe.

Funder

Narodowe Centrum Nauki

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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