Mechanistic study of the cooperative palladium/Lewis acid-catalyzed transfer hydrocyanation reaction: the origin of the regioselectivity-Reference-Cited by-同舟云学术

Mechanistic study of the cooperative palladium/Lewis acid-catalyzed transfer hydrocyanation reaction: the origin of the regioselectivity

Published:2021 Issue:4 Volume:50 Page:1233-1238
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jiang Dandan¹²³⁴⁵,Li Xiaojun¹²³⁴⁵,Cai Jiali¹²³⁴⁵,Bai Yuna¹²³⁴⁵,Zhang Lixiong⁶⁷³⁴⁵,Zhao Lili¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Advanced Synthesis

2. School of Chemistry and Molecular Engineering

3. Nanjing Tech University

4. Nanjing 211816

5. China

6. College of Chemical Engineering

7. State Key Laboratory of Materials-Oriented Chemical Engineering

Abstract

DFT calculations were performed to gain insights into the catalytic mechanism of the palladium/Lewis acid-catalyzed transfer hydrocyanations. Furthermore, the origin of the excellent regioselectivity of the product is discussed.

Funder

National Natural Science Foundation of China

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03941A

Reference50 articles.

1. Transformations of X (C, O, N)–CN bonds: cases of selective X (C, O, N)–C activation

2. Recent advances in transition-metal-catalyzed C–CN bond activations

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4. Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

5. An asymmetric hydrocyanation/Michael reaction of α-diazoacetates via Cu(i)/chiral guanidine catalysis

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