Palladium particle-catalyzed selective butadiene hydrogenation: effect of covalent organic framework modification

Author:

Li Xianming1,Wang Yi2,Yuan Qiao34ORCID,Chen Xintai2,Mou Xiaoling25,Song Xiangen3,Yan Li3,Lin Ronghe25,Ding Yunjie236ORCID

Affiliation:

1. Hangzhou Qingfan Advanced Material Co., Ltd., D118, Science and Technology Park of Hangzhou Normal University, 1378 Wenyi West Road, Hangzhou 311121, China

2. Hangzhou Institute of Advanced Studies, Zhejiang Normal University, 1108 Gengwen Road, Hangzhou 311231, China

3. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China

4. University of Chinese Academy of Sciences, Beijing 100049, China

5. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, 688 Yingbin Road, Jinhua 321004, China

6. The State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China

Abstract

Deposition of a covalent organic framework on palladium nanoparticles induces geometric and electronic effects on the metal species and improves their selective performance in 1,3-butadiene hydrogenation.

Funder

National Natural Science Foundation of China

Zhejiang Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

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