Stereoselective oxidation of alkanes with m-CPBA as an oxidant and cobalt complex with isoindole-based ligands as catalysts
Author:
Affiliation:
1. Centro de Química Estrutural
2. Instituto Superior Técnico
3. Universidade de Lisboa
4. 1049-001 Lisboa
5. Portugal
Abstract
Coordination compound of cobalt catalyses hydroxylation of inert C–H bonds with 98% retention of stereoconfiguration of alkane skeleton.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA14382B
Reference59 articles.
1. Understanding and exploiting C–H bond activation
2. If CH Bonds Could Talk: Selective CH Bond Oxidation
3. Adding Aliphatic C–H Bond Oxidations to Synthesis
4. CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals
5. C–H functionalization logic in total synthesis
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