Highly efficient and enantioselective synthesis of chiral lactones <i>via</i> Ir-catalysed asymmetric hydrogenation of ketoesters-Reference-Cited by-同舟云学术

Highly efficient and enantioselective synthesis of chiral lactones via Ir-catalysed asymmetric hydrogenation of ketoesters

Published:2022 Issue:60 Volume:58 Page:8408-8411
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Song Jingyuan¹²,Yin Congcong²,Zhang Yao²,Shi Yongjie²,Li Yingjun³⁴,Chen Gen-Qiang⁴^ORCID,Zhang Xumu²³^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

2. Department of Chemistry, Southern University of Science and Technology, 1088 Xueyuan Road, Shenzhen, 518055, China

3. Shenzhen Bay Laboratory, Shenzhen 518132, China

4. Academy for Advanced Interdisciplinary Studies, Department of Chemistry, Southern University of Science and Technology, 1088 Xueyuan Road, Shenzhen, 518055, China

Abstract

We herein report an efficient asymmetric hydrogenation of ketoesters catalyzed by chiral iridium complex bearing ferrocene-based chiral ligands, furnishing a series of chiral lactones with up to 99% yield and up to 99% ee.

Funder

National Natural Science Foundation of China

Shenzhen Bay Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02069F

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