Dinuclear helicate or mononuclear pincer lanthanide complexes from one ligand: stereo-controlled assembly and catalysis-Reference-Cited by-同舟云学术

Dinuclear helicate or mononuclear pincer lanthanide complexes from one ligand: stereo-controlled assembly and catalysis

Published:2021 Issue:11 Volume:8 Page:2576-2582
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Ran¹²³⁴⁵,Yan Qian-Qian¹²³⁴⁵,Hu Shao-Jun⁵⁶⁷⁸⁴,Guo Xiao-Qing⁵⁶⁷⁸⁴,Cai Li-Xuan⁵⁶⁷⁸⁴^ORCID,Yan Dan-Ni⁵⁶⁷⁸⁴,Zhou Li-Peng⁵⁶⁷⁸⁴^ORCID,Sun Qing-Fu¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry

2. Fuzhou University

3. Fuzhou 350108

4. People's Republic of China

5. State Key Laboratory of Structural Chemistry

6. Fujian Institute of Research on the Structure of Matter

7. Chinese Academy of Sciences

8. Fuzhou 350002

Abstract

By varying the metal/ligand ratio, either dinuclear triple helicate or mononuclear pincer can be stereo-selectively obtained from the same chiral ligand. Their catalytic properties have been demonstrated with the asymmetric FC alkylation reactions.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00369K

Reference73 articles.

1. Cerium-Based M4L4Tetrahedra as Molecular Flasks for Selective Reaction Prompting and Luminescent Reaction Tracing

2. The First Europium(III) β-Diketonate Complex Functionalized Polyhedral Oligomeric Silsesquioxane