Synthesis and characterization of rhodium–aluminum heterobimetallic complexes tethered by a 1,3-bis(diphenylphosphino)-2-propanoxy group-Reference-Cited by-同舟云学术

Synthesis and characterization of rhodium–aluminum heterobimetallic complexes tethered by a 1,3-bis(diphenylphosphino)-2-propanoxy group

Published:2019 Issue:24 Volume:48 Page:8782-8790
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Zhongjing¹²³⁴,Yokley Timothy W.¹²³⁴^ORCID,Tran Sheila L.¹²³⁴,Zong Jie¹⁵⁴,Schley Nathan D.¹⁶⁷⁴^ORCID,Brewster Timothy P.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. The University of Memphis

3. Memphis

4. USA

5. The Pennsylvania State University

6. Vanderbilt University

7. Nashville

Abstract

We demonstrate the synthesis and characterization of a new class of late transition metal-aluminum heterobimetallic complexes. A bridging ligand which both chelates the transition metal and binds the aluminum via an alkoxide was employed to impart stability to the bimetallic system.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00938H

Reference44 articles.

1. Heterobimetallic Complexes for Theranostic Applications

2. Easy access to heterobimetallic complexes for medical imaging applications via microwave-enhanced cycloaddition

3. IrIII/AuI and RhIII/AuI Heterobimetallic Complexes as Catalysts for the Coupling of Nitrobenzene and Benzylic Alcohol

4. A heterobimetallic complex featuring a Ti–Co multiple bond and its application to the reductive coupling of ketones to alkenes

5. Structure and Reactivity of Early−Late Heterobimetallic Complexes

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. H2 and carbon-heteroatom bond activation mediated by polarized heterobimetallic complexes;Coordination Chemistry Reviews;2021-04

2. Heterobimetallic Complexes of 1,1-Diphosphineamide Ligands;Organometallics;2021-01-08

3. Rhodium and iridium NNO-Scorpionate complexes: synthesis, structure, and reactivity with aluminum alkyls;Inorganica Chimica Acta;2020-06

4. Synthesis and Electronic Characterization of Iridium‐Aluminum and Rhodium‐Aluminum Heterobimetallic Complexes Bridged by 3‐Oxypyridine and 4‐Oxypyridine;European Journal of Inorganic Chemistry;2020-03-06