Tuning of exchange coupling by the Mn–O distance and phenoxido bridging angle: an experimental and theoretical study of the family of Mn(iii) dimers with salen type ligands
Author:
Affiliation:
1. Department of Chemistry
2. University College of Science
3. University of Calcutta
4. Kolkata 700 009
5. India
Abstract
Three new Mn(iii) complexes of salen type Schiff base ligands have been synthesized in order to correlate their magnetic properties with structural parameters, theoretically and experimentally.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01224D
Reference34 articles.
1. A novel manganese(III) quadridentate Schiff-base dimeric complex: synthesis, crystal structure and magnetic properties
2. Syntheses, Crystal Structures, and Magnetic Characterization of Five New Dimeric Manganese(III) Tetradentate Schiff Base Complexes Exhibiting Single-Molecule-Magnet Behavior
3. SYNTHESIS AND CRYSTAL STRUCTURE OF A MANGANESE(III) COMPLEX WITH THE TETRADENTATE SCHIFF BASEN,N′-ETHYLENEBIS(SALICYLIDENEIMINATO)
4. Out-of-plane dimers of Mn(iii) quadridentate Schiff-base complexes with saltmen2– and naphtmen2– ligands: structure analysis and ferromagnetic exchange
5. [MIII(dmit)2]−-Coordinated MnIII Salen-Type Dimers (MIII = NiIII, AuIII; dmit2− = 1,3-Dithiol-2-thione-4,5-dithiolate): Design of Single-Component Conducting Single-Molecule Magnet-Based Materials
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