A recyclable cobalt(iii)–ammonia complex catalyst for catalytic epoxidation of olefins with air as the oxidant-Reference-Cited by-同舟云学术

A recyclable cobalt(iii)–ammonia complex catalyst for catalytic epoxidation of olefins with air as the oxidant

Published:2021 Issue:4 Volume:45 Page:2147-2156
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wang Chenlong¹²³,Zhan Hongju⁴⁵³,Lu Xinhuan¹²³,Jing Run¹²³,Zhang Haifu¹²³,Yang Lu¹²³,Li Xixi¹²³,Yue Fanfan¹²³,Zhou Dan¹²³^ORCID,Xia Qinghua¹²³^ORCID

Affiliation:

1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Ministry-of-Education Key Laboratory for Green Preparation and Application of Functional Materials, Hubei University

2. Wuhan 430062

3. P. R. China

4. Jingchu University of Technology

5. Jingmen 448000

Abstract

A recyclable [Co(NH₃)₆]Cl₃ complex was synthesized to catalyze the epoxidation of α-pinene. With air as the oxidant, [Co(NH₃)₆]Cl₃ obtained 97.4% conversion of α-pinene and 98.3% selectivity of epoxide.

Funder

National Natural Science Foundation of China

Wuhan Municipal Science and Technology Bureau

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ05466F

Reference55 articles.

1. Organocatalytic Oxidation. Asymmetric Epoxidation of Olefins Catalyzed by Chiral Ketones and Iminium Salts

2. Switching on the Electrocatalytic Ethene Epoxidation on Nanocrystalline RuO2