Understanding the different effects of 4d-transition metals on the performance of Li-rich cathode Li<sub>2</sub>MnO<sub>3</sub> by first-principles-Reference-Cited by-同舟云学术

Understanding the different effects of 4d-transition metals on the performance of Li-rich cathode Li₂MnO₃ by first-principles

Published:2023 Issue:3 Volume:25 Page:2282-2293
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhang Shiwei¹^ORCID,Wang Jianchuan¹^ORCID,Tao Xiaoma²,Yan Xiangyu¹,Du Yong¹,Seifert Hans J.³,Lei Ting¹

Affiliation:

1. State Key Laboratory of Powder Metallurgy, Central South University, 410083, Changsha, China

2. School of Physical Science and Technology, Guangxi University, 530004, Nanning, China

3. Institute for Applied Materials, Karlsruhe Institute of Technology, Karlsruhe, 76131, Germany

Abstract

The doping effects of transition metals with various numbers of d electrons on Li2MnO3 are different. The summary of variation of the charge compensation mechanism facilitates the design of Li-rich cathodes.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP04271A

Reference55 articles.

1. Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries

2. Reversible anionic redox chemistry in high-capacity layered-oxide electrodes

3. Reactive template synthesis of Li1.2Mn0.54Ni0.13Co0.13O2 nanorod cathode for Li-ion batteries: Influence of temperature over structural and electrochemical properties

4. Li-Rich Layered Oxides and Their Practical Challenges: Recent Progress and Perspectives

5. High-voltage positive electrode materials for lithium-ion batteries

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