Electrochemical phosphorothiolation and 1,4-S → C phospho-Fries rearrangement: controlled access to phosphorothiolated and mercapto-phosphono substituted indolizines-Reference-Cited by-同舟云学术

Electrochemical phosphorothiolation and 1,4-S → C phospho-Fries rearrangement: controlled access to phosphorothiolated and mercapto-phosphono substituted indolizines

Published:2023 Issue:20 Volume:10 Page:5198-5204
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Xiang¹^ORCID,Jiang Wenxuan¹,Huang Changfeng¹,Ma Shaohong¹,Wang Qiong¹,Cao Hua¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Guangdong Provincial Key Laboratory of Advanced Drug Delivery, and Guangdong Provincial Engineering Center of Topical Precise Drug Delivery System, Guangdong Pharmaceutical University, Zhongshan 528458, China

Abstract

An unprecedented electrochemically regioselective C–H phosphorothiolation and S- to C-[1,4] phosphonyl migration involving indolizines, elemental sulfur, and H-phosphonates in an undivided cell has been developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO01042B

Reference63 articles.

1. Synthesis, Properties, and Applications of Oligonucleotides Containing an RNA Dinucleotide Phosphorothiolate Linkage

2. Synthesis of Phosphorus and Sulfur Heterocycles via Ring-Closing Olefin Metathesis

3. A Berzelius Reagent, Phosphorus Decasulfide (P4S10), in Organic Syntheses