Expanding new chemistry of aza-boracyclophanes with unique dipolar structures, AIE and redox-active open-shell characteristics-Reference-Cited by-同舟云学术

Expanding new chemistry of aza-boracyclophanes with unique dipolar structures, AIE and redox-active open-shell characteristics

Published:2022 Issue:39 Volume:13 Page:11672-11679
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jia Yawei¹,Li Pengfei¹,Liu Kanglei¹,Li Chenglong¹,Liu Meiyan¹,Di Jiaqi¹,Wang Nan¹^ORCID,Yin Xiaodong¹^ORCID,Zhang Niu²,Chen Pangkuan¹^ORCID

Affiliation:

1. Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China, Beijing, 102488, China

2. Analysis & Testing Centre, Beijing Institute of Technology of China, Beijing, 102488, China

Abstract

We have achieved the synthesis of new B/N doped macrocycles by stitching oligoarylamine pentamers using arylborane acceptor segments. They exhibit open-shell radical species and AIE under ambient conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03581B

Reference86 articles.

1. Ball-, Bowl-, and Belt-Shaped Conjugated Systems and Their Complexing Abilities: Exploration of the Concave−Convex π−π Interaction

2. Conjugated Macrocycles: Concepts and Applications

3. Nitrogen and Oxygen Bridged Calixaromatics: Synthesis, Structure, Functionalization, and Molecular Recognition