Chasing the agostic interaction in ligand assisted cyclometallation reactions of palladium(ii)-Reference-Cited by-同舟云学术

Chasing the agostic interaction in ligand assisted cyclometallation reactions of palladium(ii)

Published:2017 Issue:46 Volume:46 Page:16126-16138
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sajjad M. Arif¹²³⁴⁵,Christensen Kirsten E.⁶⁷⁸⁹¹⁰,Rees Nicholas H.⁶⁷⁸⁹¹⁰,Schwerdtfeger Peter¹¹¹²³⁴⁵,Harrison John A.¹²³⁴⁵^ORCID,Nielson Alastair J.¹²³⁴⁵^ORCID

Affiliation:

1. Chemistry

2. Institute of Natural and Mathematical Sciences

3. Massey University Auckland

4. Auckland

5. New Zealand

6. Inorganic Chemistry Laboratory

7. Department of Chemistry

8. University of Oxford

9. Oxford

10. UK

11. Centre for Theoretical and Physics

12. The New Zealand Institute for Advanced Study

Abstract

Computations show that a possible aromatic ring agostic intermediate seen by NMR spectroscopy in a cyclometallation reaction by palladium(ii) can involve CCπ electron density close to the agostic carbon being donated to the metal.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03525J

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