Unprecedented flexibility of the 1,1′-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B–H⇀Ru interactions-Reference-Cited by-同舟云学术

Unprecedented flexibility of the 1,1′-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B–H⇀Ru interactions

Published:2016 Issue:3 Volume:45 Page:1127-1137
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Riley Laura E.¹²³⁴,Chan Antony P. Y.¹²³⁴,Taylor James¹²³⁴,Man Wing Y.¹²³⁴,Ellis David¹²³⁴,Rosair Georgina M.¹²³⁴,Welch Alan J.¹²³⁴,Sivaev Igor B.⁵⁶⁷⁸

Affiliation:

1. Institute of Chemical Sciences

2. Heriot-Watt University

3. Edinburgh

4. EH14 4AS UK

5. A. N. Nesmeyanov Institute of Organoelement Compounds

6. Russian Academy of Sciences

7. Moscow

8. Russia

Abstract

The compound (p-cymene)Ru[(C₂B₁₀H₁₀)₂], an effective Lewis acid catalyst, is the precursor to a number of products in which the 1,1′-bis(o-carborane) unit displays an unprecedented range of ligating modes.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03417E

Reference62 articles.

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4. Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)]

5. The Preparation of 1-[1,2-Dicarbaclovododecaboranyl(12)]-1,2-dicarbaclovododecaborane(12)

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