Solubilized LiNO<sub>3</sub>by the cationic size effect of CsF for lithium metal anode protection and dendrite formation prevention in carbonate electrolyte-Reference-Cited by-同舟云学术

Solubilized LiNO₃by the cationic size effect of CsF for lithium metal anode protection and dendrite formation prevention in carbonate electrolyte

Published:2023 Issue:6 Volume:10 Page:1809-1817
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhao Jing¹,Wan Zhengwei¹,Zeng Xiaomin¹,Tian Miaomiao¹,Wang Kun¹,Chen Xinyu¹,Ling Min¹²^ORCID,Ni Wenbin²,Liang Chengdu¹²

Affiliation:

1. College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China

2. Institute of Zhejiang University-Quzhou, 78 Jiuhua Boulevard North, Quzhou, 324000, China

Abstract

CsF solubilized LiNO3 to optimize solvated shell of Li+ in carbonate electrolyte. LiF-rich SEI was generated to prevent severe side reactions of Li metal. Cs+ can inhibit lithium dendrite formation by self-healing electrostatic shield mechanism.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI02416K

Reference31 articles.

1. Back to the basics: Advanced understanding of the as-defined solid electrolyte interphase on lithium metal electrodes

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