Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF

Author:

Lee Li-Wei12345,Kao Ya-Chuan1234,Chung Mei-Ying1234,Chang Bor-Chen6784,Lee Gene-Hsiang69104,Peng Shie-Ming69104,Wang Chih-Min1112134ORCID,Liu Yen-Hsiang614154,Lee Sheng-Long5784,Lu Kuang-Lieh12345

Affiliation:

1. Institute of Chemistry

2. Academia Sinica

3. Taipei 115

4. Taiwan

5. Institute of Materials Science and Engineering

6. Department of Chemistry

7. National Central University

8. Taoyuan 320

9. National Taiwan University

10. Taipei 107

11. Department of Bioscience and Biotechnology

12. National Taiwan Ocean University

13. Keelung 202

14. Fu Jen Catholic University

15. Taipei 242

Abstract

An SHG-active framework of 1-Zn can undergo metal metathesis, in which the tetrahedrally coordinated Zn(ii) ions are completely exchanged with Cu(ii) ions while retaining the integrity of the network.

Funder

Academia Sinica

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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