Synthesis of (Z)-β-halo α,β-unsaturated carbonyl systems via the combination of halotrimethylsilane and tetrafluoroboric acid

Author:

da Silva Vitor A. F.12345ORCID,da Silva Gustavo P.12345,Matsuo Bianca T.12345,Ali Akbar12345,Davis Rebecca L.2678ORCID,Zukerman-Schpector Julio12345,Corrêa Arlene G.12345ORCID,Paixão Márcio W.12345ORCID

Affiliation:

1. Centre of Excellence for Research in Sustainable Chemistry (CERSusChem)

2. Department of Chemistry

3. Federal University of São Carlos – UFSCar

4. São Carlos

5. Brazil

6. University of Manitoba

7. Winnipeg

8. Canada

Abstract

A procedure for the stereoselective synthesis of β-halovinyl derivatives via a conjugate addition of HX to ynones has been developed.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Instituto Nacional de Ciência e Tecnologia de Catálise em Sistemas Moleculares e Nanoestruturados

Fundação de Amparo à Pesquisa do Estado de São Paulo

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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