Acid catalysis through N-protonation in undistorted carboxamides: improvement of amide proton sponge acylating ability-Reference-Cited by-同舟云学术

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Acid catalysis through N-protonation in undistorted carboxamides: improvement of amide proton sponge acylating ability

Published:2022 Issue:34 Volume:46 Page:16471-16484
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mikshiev Vladimir Y.¹^ORCID,Tolstoy Peter M.¹^ORCID,Tupikina Elena Yu.¹^ORCID,Puzyk Aleksandra M.¹^ORCID,Vovk Mikhail A.¹^ORCID

Affiliation:

1. Institute of Chemistry, St. Petersburg State University, Universitetskij pr. 26, 198504 St. Petersburg, Russian Federation

Abstract

Molecular design by means of quantum-chemistry to improve an acid catalysed acyl-migration reaction through protonated amide nitrogen atom in carboxamides.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ02975H

Reference71 articles.

1. An update of biocatalytic selective acylation and deacylation of monosaccharides

2. Analysis of the reactions used for the preparation of drug candidate molecules

3. Survey of GMP Bulk Reactions Run in a Research Facility between 1985 and 2002

4. Critical Assessment of Pharmaceutical ProcessesA Rationale for Changing the Synthetic Route

5. Achieving synthetic efficiency through new method development

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