Synthesis, regioselective aerobic Pd(ii)-catalyzed C–H bond alkenylation and the photophysical properties of pyrenylphenylpyrazoles

Author:

Flamholc Rafał12345,Zakrzewski Janusz12345,Makal Anna6785,Brosseau Arnaud910111213,Métivier Rémi910111213

Affiliation:

1. Department of Organic Chemistry

2. Faculty of Chemistry

3. University of Łódź

4. 91-403 Łódź

5. Poland

6. University of Warsaw

7. Biological and Chemical Research Center

8. 02-089 Warszawa

9. PPSM

10. ENS Cachan

11. CNRS

12. UniverSud

13. 94230 Cachan

Abstract

Pd(ii)-catalyzed C–H alkenylation of a pyrenylphenylpyrazole afforded fluorophore exhibiting solvent-dependent dual emission, resulting from locally-excited (LE) and intramolecular charge transfer (ICT) excited states.

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry

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