Elucidating the chemical dynamics of the elementary reactions of the 1-propynyl radical (CH3CC; X2A1) with 2-methylpropene ((CH3)2CCH2; X1A1)-Reference-Cited by-同舟云学术

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Elucidating the chemical dynamics of the elementary reactions of the 1-propynyl radical (CH₃CC; X²A₁) with 2-methylpropene ((CH₃)₂CCH₂; X¹A₁)

Published:2024 Issue:7 Volume:26 Page:6448-6457
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Medvedkov Iakov A.¹^ORCID,Nikolayev Anatoliy A.²^ORCID,Yang Zhenghai¹,Goettl Shane J.¹^ORCID,Mebel Alexander M.³^ORCID,Kaiser Ralf I.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Hawai‘i at Manoa, Honolulu, HI 96822, USA

2. Samara National Research University, Samara 443086, Russia

3. Department of Chemistry and Biochemistry, Florida International University, Miami, Florida 33199, USA

Abstract

Exploiting the crossed molecular beam technique, we studied the reaction of the 1-propynyl radical with 2-methylpropene (isobutylene) preferentially leading to trimethylvinylacetylene. This reaction is feasible in cold molecular clouds.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP05872G

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