Insights into the reaction mechanism of CO oxidative coupling to dimethyl oxalate over palladium: a combined DFT and IR study
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry
2. Key Laboratory of Coal to Ethylene Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fuzhou 350002
5. P. R. China
Abstract
Oxidative coupling of toxic pollutant CO to form the platform raw chemical material dimethyl oxalate (DMO) has been industrialized however the catalytic mechanism has been unknown so far.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05738D
Reference71 articles.
1. Cu/SiO2 Catalysts Prepared by the Sol-Gel Method for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol
2. Cu/SiO2 catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol
3. High activity and selectivity of Ag/SiO2 catalyst for hydrogenation of dimethyl oxalate
4. Effect of feedstock solvent on the stability of Cu/SiO2catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol
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