Synthesis of triarylphosphines from arylammonium salts <i>via</i> one-pot transition-metal-free C

Synthesis of triarylphosphines from arylammonium salts via one-pot transition-metal-free C–P coupling

Published:2022 Issue:19 Volume:20 Page:3897-3901
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhang Lei¹,Liu Chengyu¹,Yang Lei¹,Cao Liming¹,Liang Chaoming²,Sun Maolin²,Ma Yueyue²,Cheng Ruihua²,Ye Jinxing¹²^ORCID

Affiliation:

1. Engineering Research Centre of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

2. School of Biomedical and Pharmaceutical Sciences, Guangdong University of Technology, Guangzhou 510006, China

Abstract

The one-pot coupling of arylammonium salts and secondary phosphines from the in situ reduction of diarylphosphine oxides via SNAr reaction for the transition-metal-free synthesis of triarylphosphines is reported.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00547F

Reference71 articles.

1. Vitamin B12. XVI.1,2 Modifications of Cyano-cobalamin

2. Microbial Epoxidation of cis -Propenylphosphonic to (−)- cis -1,2-Epoxypropylphosphonic Acid

3. Preclinical pharmacology of CGP 42′446, a new, potent, heterocyclic bisphosphonate compound

4. Prevention of SIV Infection in Macaques by ( R )-9-(2-Phosphonylmethoxypropyl)adenine

5. An enzyme inhibition assay for the quantitative determination of the new bisphosphonate zoledronate in plasma

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The Preparation of Diaryl Sulfoxinium Triflates and Their Application in Palladium‐Catalyzed Cross‐Coupling Reactions;Chemistry – An Asian Journal;2022-08-29