Modulating magnetic dynamics through tailoring the terminal ligands in Dy2 single-molecule magnets

Author:

Cen Peipei12345,Liu Xiangyu678910ORCID,Zhang Yi-Quan111213145ORCID,Ferrando-Soria Jesús1516171819ORCID,Xie Gang12345,Chen Sanping12345ORCID,Pardo Emilio1516171819ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education

2. College of Chemistry and Materials Science

3. Northwest University

4. Xi'an 710069

5. China

6. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering

7. National Demonstration Center for Experimental Chemistry Education

8. College of Chemistry and Chemical Engineering

9. Ningxia University

10. Yinchuan 750021

11. Jiangsu Key Laboratory for NSLSCS

12. School of Physical Science and Technology

13. Nanjing Normal University

14. Nanjing 210023

15. Departamento de Química Inorgánica

16. Instituto de Ciencia Molecular (ICMOL)

17. Universidad de Valencia

18. Paterna 46980

19. Spain

Abstract

The alternation of terminal ligands leads to distinct arrangements of anisotropy axes and magnetic interactions in two Dy2 complexes which present different dynamic magnetic behaviors.

Funder

National Natural Science Foundation of China

Ministerio de Economía y Competitividad

Universitat de València

“la Caixa” Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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