Large and negative magnetic anisotropy in pentacoordinate mononuclear Ni(ii) Schiff base complexes-Reference-Cited by-同舟云学术

Large and negative magnetic anisotropy in pentacoordinate mononuclear Ni(ii) Schiff base complexes

Published:2015 Issue:20 Volume:44 Page:9551-9560
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nemec Ivan¹²³⁴⁵^ORCID,Herchel Radovan¹²³⁴⁵^ORCID,Svoboda Ingrid⁶⁷⁸⁹,Boča Roman¹⁰¹¹¹²¹³¹⁴,Trávníček Zdeněk¹²³⁴⁵

Affiliation:

1. Regional Centre of Advanced Technologies and Materials

2. Department of Inorganic Chemistry

3. Faculty of Science

4. Palacký University

5. CZ-77146 Olomouc

6. Materials Science

7. Darmstadt University of Technology

8. Darmstadt

9. Germany

10. Department of Chemistry

11. FPV

12. University of SS Cyril and Methodius

13. 91701 Trnava

14. Slovakia

Abstract

Pentacoordinate Ni(ii) complexes with pentadentate Schiff base ligands possess large and negative values of axial magnetic anisotropy. The relationship between the shape of the coordination polyhedron and uniaxial anisotropy is outlined.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00600G

Reference80 articles.

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