Site-selective formation of an iron(iv)–oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines-Reference-Cited by-同舟云学术

Site-selective formation of an iron(iv)–oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines

Published:2015 Issue:8 Volume:6 Page:5063-5075
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

İşci Ümit¹²³⁴^ORCID,Faponle Abayomi S.⁵⁶⁷⁸^ORCID,Afanasiev Pavel⁹¹⁰¹¹¹²¹³,Albrieux Florian¹⁴¹⁵¹⁶¹⁷¹⁸,Briois Valérie¹⁹²⁰¹³,Ahsen Vefa¹²³⁴,Dumoulin Fabienne¹²³⁴^ORCID,Sorokin Alexander B.⁹¹⁰¹¹¹²¹³,de Visser Sam P.⁵⁶⁷⁸^ORCID

Affiliation:

1. Gebze Technical University

2. Department of Chemistry

3. 41400 Kocaeli

4. Turkey

5. Manchester Institute of Biotechnology and School of Chemical Engineering and Analytical Science

6. The University of Manchester

7. Manchester M1 7DN

8. UK

9. Institut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON)

10. UMR 5256

11. CNRS-Université Lyon 1

12. 69626 Villeurbanne Cedex

13. France

14. Centre Commun de Spectrométrie de Masse UMR 5246

15. CNRS-Université Claude Bernard Lyon 1

16. Université de Lyon

17. Bâtiment Curien

18. 69622 Villeurbanne Cedex

19. Synchrotron Soleil

20. 91192 Gif-sur-Yvette

Abstract

A combination of MS and computation on μ-nitrido bridged diiron complexes reveals H₂O₂ binding to the complex and generates an oxidant capable of oxidizing methane.

Funder

Scientific and Technological Research Council of Turkey

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01811K

Reference116 articles.

1. Stalking intermediates in oxygen activation by iron enzymes: Motivation and method

2. High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions

3. Heme-Containing Oxygenases