Vanadyl β-tetrabromoporphyrin: synthesis, crystal structure and its use as an efficient and selective catalyst for olefin epoxidation in aqueous medium
Author:
Affiliation:
1. Department of Chemistry
2. Indian Institute of Technology Roorkee
3. Roorkee
4. India
5. Graduate School of Science
6. Tohoku University
7. Sendai 980-8578
8. Japan
Abstract
We have synthesized β-tetrabromo-meso-tetraphenylporphyrinatooxidovanadium(iv) (VOTPPBr4) which possesses high thermal stability and nonplanar macrocyclic core. Further, it was utilized for selective epoxidation of olefins in good yields with very high TOF numbers.
Funder
Science and Engineering Research Board
Ministry of Human Resource Development
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/RA/C8RA09825E
Reference72 articles.
1. K.Weissermel and H. J.Arpe , Industrial organic chemistry , VCH , 1997
2. Recent advances in the preparation and synthetic applications of oxiranes
3. Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?
4. Vanadium Peroxide Complexes
5. Reaction Mechanisms of Mononuclear Non-Heme Iron Oxygenases
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