The role of zero-field splitting and π-stacking interaction of different nitrogen-donor ligands on the optical properties of luminescent rhenium tricarbonyl complexes

Author:

Cantero-López Plinio12345ORCID,Hidalgo-Rosa Yoan63758,Sandoval-Olivares Zoraida6375,Santoyo-Flores Julián6375,Mella Pablo63753,Arrué Lily6375,Zúñiga César910111213,Arratia-Pérez Ramiro12345ORCID,Páez-Hernández Dayán12345

Affiliation:

1. Center of Applied Nanoscience (CANS)

2. Facultad de Ciencias Exactas

3. Universidad Andres Bello

4. Santiago

5. Chile

6. Doctorado en Fisicoquímica Molecular

7. Santiago de Chile

8. ANID – Millennium Science Initiative Program- Millennium Nuclei on Catalytic Process towards Sustainable Chemistry (CSC)

9. Instituto de Ciencias Naturales

10. Facultad de Medicina Veterinaria y Agronomía

11. Universidad de Las Américas

12. Sede Providencia

13. 7500972 Santiago

Abstract

In this work, a systematic evaluation of the role of zero-field splitting (ZFS), and the geometric arrangement of different nitrogen-donor ligands, including π-stacking interactions, in five selected rhenium luminescent complexes was performed.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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