The superiority of Pd<sup>2+</sup> in CO<sub>2</sub> hydrogenation to formic acid-Reference-Cited by-同舟云学术

The superiority of Pd²⁺ in CO₂ hydrogenation to formic acid

Published:2024 Issue:15 Volume:15 Page:5525-5530
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Yanyan¹²,Dong Minghua²³,Li Shaopeng²³,Chen Bingfeng²^ORCID,Liu Huizhen²³^ORCID,Han Buxing²³^ORCID

Affiliation:

1. National Narcotics Laboratory Beijing Regional Center, Beijing 100164, P. R. China

2. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

3. School of Chemical Science, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The hydrogenation of CO2 to formic acid is catalyzed for the first time by a Pd2+ catalyst, Pd–V/AC–air. The superiority of Pd2+ over Pd0 is confirmed by a combination of DFT and experimental results.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06925G

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