Confined dual Lewis acid centers for selective cascade C–C coupling and deoxygenation-Reference-Cited by-同舟云学术

Confined dual Lewis acid centers for selective cascade C–C coupling and deoxygenation

Published:2024 Issue:21 Volume:15 Page:8031-8037
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Houqian¹^ORCID,Pang Jifeng²^ORCID,Hu Wenda¹³,Caballero Vannessa¹^ORCID,Sun Junming¹^ORCID,Tan Mingwu⁴,Hu Jian Zhi³^ORCID,Ni Yelin³,Wang Yong¹³^ORCID

Affiliation:

1. The Gene & Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164, USA

2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No. 457 Zhongshan Road, Dalian 116023, P.R. China

3. Pacific Northwest National Laboratory, Richland, WA 99352, USA

4. Institute of Sustainability for Chemicals, Energy and Environment, 1 Pesek Road Jurong Island, 627833, Singapore

Abstract

Dual Lewis acidic centers, CeOx and framework Sn, confined in Beta zeolite, catalyze the acetone C–C coupling followed by deoxygenation to isobutene, achieving a desirable product distribution and stability in the absence of water.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06921D

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