PHOTOCHROMIC LIGANDS FOR MODIFICATION OF METAL CATIONS AND QUANTUM DOTS

Author:

Belikov N.1,Demina O.1,Levina I.2,Lukin A.3,Safinova A.3,Petrovskaya L.4,Varfolomeev Sergey56,Khodonov A.1

Affiliation:

1. N.M. Emanuel Institute of Biochemical Physics RAS

2. N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences

3. MIREA - Russian Technological University

4. Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry RAS

5. Emanuel Institute of Biochemical Physics Russian Academy of Sciences

6. Lomonosov Moscow State University

Abstract

In this paper, we consider the studies carried out by the authors aimed at developing new hybrid structures and methods for obtaining a family of photochromic labels capable of photocontrolled interaction with inorganic components, as well as the results of studying their photochromic behavior and the selectivity of complex formation processes. In this paper, special attention is devoted to the choice of the desired composition and structure of label molecules and the practical implementation of laboratory technology for the synthesis of a set of target compounds with specified optical parameters. The data obtained open up prospects for the use of a new generation of photochromes based on functionalized spiropyrans as new hybrid materials for the creation on their basis: metal detectors, components of photochromic systems, and prototypes of molecular electronics smart devices.

Publisher

RIOR Publishing Center

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