High-pressure phase transitions in the rare-earth orthoferrite LaFeO3

Abstract

Sequential Rietveld refinements were applied on high-pressure synchrotron powder X-ray diffraction measurements of lanthanum ferrite (LaFeO3) revealing two phase transitions on the room-temperature isotherm up to a pressure of 48 GPa. The first structural phase transition of second order occurs at a pressure of 21.1 GPa, changing the space group fromPbnmtoIbmm. The second transition, involving a isostructural first-order phase transition, occurs at approximately 38 GPa, indicating a high-spin to low-spin transition of the Fe3+ion. Following the behavior of the volume up to the hydrostatic limit of methanol–ethanol it was possible to use inverted equations of state (EoS) to determine a bulk modulus ofB0= 172 GPa and a corresponding pressure derivative ofB′0= 4.3. In addition, the linearized version of the inverted EoS were used to determine the corresponding moduli and pressure derivatives for each lattice direction.