A novel polytype – the stacking fault based γ-MoO3nanobelts

Abstract

γ-MoO3nanobelts prepared by hydrothermal synthesis were studied by synchrotron radiation powder diffraction, scanning electron microscopy, transmission electron microscopy and selected area electron diffraction. Their nm dimensions, in particular in two crystallographic directions, have a profound influence on electrochemical properties during cycling as the cathode material in lithium-ion batteries (LIBs). The diffraction analysis shows clearly that the crystal structure for the γ-MoO3nanobelts differs significantly from that of bulk α-MoO3. The observed powder diffraction pattern, with asymmetric peaks, extremely broad peaks, as well as additional or absent diffraction peaks, is fully described by means of a model based on stacking disorder of MoO3slabs.