Pseudosymmetry in a cyclopalladated compound-Reference-Cited by-同舟云学术

Pseudosymmetry in a cyclopalladated compound

Published:2012-07-19 Issue:8 Volume:68 Page:m223-m225
ISSN:0108-2701
Container-title:Acta Crystallographica Section C Crystal Structure Communications
language:
Short-container-title:Acta Crystallogr C

Author:

Raven William,Kalf Irmgard,Englert Ulli

Abstract

The enantiomerically pure title complex, [SP-4-4]-(R)-[2-(1-aminoethyl)phenyl-κ2C1,N]chlorido(quinoline-κN)palladium(II) acetone hemisolvate, [Pd(C8H10N)Cl(C9H7N)]·0.5C3H6O, crystallizes with four molecules of the organopalladium complex and two molecules of acetone in the asymmetric unit. This corresponds to a discrete hydrogen-bonded aggregate and to the content of the unit cell in the space groupP1. Pronounced pseudo-inversion symmetry relates pairs of these objects in the asymmetric unit.

Publisher

International Union of Crystallography (IUCr)

Subject

General Biochemistry, Genetics and Molecular Biology,General Medicine

Link

http://journals.iucr.org/c/issues/2012/08/00/yf3015/yf3015.pdf

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