Abstract
The structure of the title one-dimensionalABX3-type organic–inorganic hybrid complex, {(C13H22N)[CdCl3]}n, consists of benzyltriethylammonium cations and one-dimensional anionic {[CdCl3]−}nchains, in which the CdIIcentres are in an unusual two-layer five-coordinated arrangement. The CdIIatom is pentacoordinated by four bridging and one terminal chloride ligand, forming a slightly distorted trigonal bipyramidal ClCd(μ-Cl)4arrangement. The trigonal bipyramid is linked by two opposite shared faces, giving rise to a zigzag linear anionic {[CdCl3]−}nchain. The benzyltriethylammonium cations are located in the inter-space of the inorganic network. There are C—H...Cl hydrogen bonds present and these play a crucial role in linking the organic cations and inorganic layers, and also help assemble the components into a three-dimensional network.
Publisher
International Union of Crystallography (IUCr)
Subject
General Biochemistry, Genetics and Molecular Biology,General Medicine
Cited by
2 articles.
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