Abstract
The title compound, [CuMo4O13(C21H15N3)2]n, was synthesized by the reaction of ammonium molybdate, copper acetate and 4-[3,5-bis(pyridin-4-yl)phenyl]pyridine (DPPP) in an aqueous medium under hydrothermal conditions. The two unique molybdenum centers and the copper center adopt MoO4tetrahedral, MoO5N octahedral and CuO4N2octahedral geometries, respectively. These polyhedra are connected to each other through corner-sharing to form a two-dimensional Cu–Mo–O layer, which is further linked by the DPPP ligands to form the three-dimensional inorganic–organic hybrid framework.
Publisher
International Union of Crystallography (IUCr)
Subject
General Biochemistry, Genetics and Molecular Biology,General Medicine
Reference38 articles.
1. Synthesis and structure of a mixed-valence tetramolybdate containing a binucleating diazene ligand
2. Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.
3. Bond-valence parameters for solids
4. Brown, I. D. (2002). The Chemical Bond in Inorganic Chemistry: the Bond Valence Model. IUCr Monographs in Crystallography, No. 12. Oxford: Oxford Science Publications.
5. Bruker (2002). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.