A two-dimensional CuIframework incorporating the 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol ligand

Abstract

The new two-dimensional coordination polymer, poly[(μ4-1-phenyl-1H-1,2,3,4-tetrazole-5-thiolato)copper(I)], [Cu(C7H5N4S)]n, has been prepared under solvothermal conditions by reacting CuBr with 1-phenyl-1H-1,2,3,4-tetrazole-5-thiol (Hptt) in an acetonitrile and acetone solution. In the crystal structure, each CuIion is coordinated by two N atoms and two S atoms from four ptt−ligands, and each ptt−ligand links four CuIions to form two-dimensional layers which lie parallel to the (100) plane. These layers stack along the [100] directionviavan der Waals interactions.