The six-membered-ring azomethineN-((E)-{5-[(E)-(pyridin-3-ylimino)methyl]thiophen-2-yl}methylidene)pyridin-3-amine-Reference-Cited by-同舟云学术

The six-membered-ring azomethineN-((E)-{5-[(E)-(pyridin-3-ylimino)methyl]thiophen-2-yl}methylidene)pyridin-3-amine

Published:2013-09-28 Issue:10 Volume:69 Page:1196-1199
ISSN:0108-2701
Container-title:Acta Crystallographica Section C Crystal Structure Communications
language:
Short-container-title:Acta Crystallogr C

Author:

Bolduc Andréanne,Dufresne Stéphane,Skene W. G.

Abstract

The title compound, C16H12N4S, forms a three-dimensional layered network structureviaintermolecular hydrogen bonding and π-stacking. The azomethine molecule adopts the thermodynamically stableEregioisomer and the pyridine substituents are antiperiplanar. The mean planes of the pyridine rings and the azomethine group to which they are connected are twisted by 27.27 (5) and 33.60 (5)°. The electrochemical energy gap of 2.3 eV based on the HOMO–LUMO energy difference is in agreement with the spectroscopically derived value.

Publisher

International Union of Crystallography (IUCr)

Subject

General Biochemistry, Genetics and Molecular Biology,General Medicine

Link

http://journals.iucr.org/c/issues/2013/10/00/lg3122/lg3122.pdf

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