Abstract
The crystal structure of perovskite LaCr1 − x
Ni
x
O3 (0 ≤ x ≤ 1.0) has been systematically investigated by analyzing X-ray powder-diffraction data taken at room temperature. Rietveld refinement has confirmed the structural evolution from the orthorhombic phase (Pbnm, Z = 4) to the two-phase (the orthorhombic and the rhombohedral phases) region around x = 0.7, then to the rhombohedral (R\bar 3c, Z = 2) phase for 0.8 ≤ x ≤ 1.0. The lattice parameters are also obtained in the refinement process. The results are discussed in terms of reduced Cr/Ni—O bond length with increasing Ni-doping level, leading to an increased tolerance factor caused by the substitution of smaller Ni3+ (R_{\rm Ni^{3 + } } = 0.60 Å, six-coordinate) ions for larger Cr3+ (R_{\rm Cr^{3 + } } = 0.615 Å, six-coordinate) ions.
Publisher
International Union of Crystallography (IUCr)
Subject
General Biochemistry, Genetics and Molecular Biology,General Medicine
Cited by
54 articles.
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