Author:
Ramesh V.,Rajarajan K.,Gunasekaran B.
Abstract
In the title compound, [Ba(C10H20O5)2][Zn(NCS)4], the 15-crown-5 molecules are disordered over two positions with site occupancies of 0.706 (4) and 0.294 (4). The Ba2+ ions are sandwiched between the 15-crown-5 rings and Zn2+ ions are surrounded by four N atoms from the thiocyanate ligands in a distorted tetrahedral geometry. The crystal studied was refined as an inversion twin.
Publisher
International Union of Crystallography (IUCr)
Subject
Rehabilitation,Physical Therapy, Sports Therapy and Rehabilitation,General Medicine
Cited by
4 articles.
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1. Synthesis, growth, structural, physicochemical, linear, and nonlinear optical properties of new hybrid [2(C10H20O5) Ba] [Co (SCN)4] single crystal;Journal of Materials Science: Materials in Electronics;2022-01-22
2. Synthesis, growth, structural, physicochemical, linear and nonlinear optical properties of new hybrid [(Ba(C10H20O5)2)· (Mn (SCN)4)] single crystal;Applied Physics A;2021-11
3. Synthesis, Growth, Structural and Physicochemical Properties of a Novel Linear and Nonlinear UV-Optical Single-Crystal for Photonic Applications: [Ba(C14H20O5)2.Co(SCN)4];ECS Journal of Solid State Science and Technology;2021-09-01
4. Bis(benzo-15-crown-5-κ5
O)barium tetrakis(isothiocyanato-κN)cobaltate(II);IUCrData;2021-01-12