Author:
Falvello Larry,Lotti Paolo,Massera Chiara,Tarantino Serena C.,Zema Michele,Puschmann Horst,Agbahoungbata Marielle Y.,Andreo Jacopo,Sahadevan Suchithra Ashoka,Bismuto Alessandro,Bonfant Giulia,Bonou Sourou A. S.,Carraro Claudia,Zotti Marta De,Biase Armando di,Fantini Riccardo,Ferraboschi Ilaria,Custodio Jean Marcos Ferreira,Frigerio Matteo,Gallo Gianpiero,Gjyli Silvana,Goudjil Meriem,Igoa Fernando,Kahveci Enver,Kalienko Maksim,Lorenzon Sofia,Macera Ludovico,Fajardo Joaqun Joaqun Manrique,Nushi Enida,Ouaatta Said,Parisi Emmanuele,Pasqualetto Leonardo,Pesko Edyta,Pierri Giovanni,Pinalli Roberta,Poppe Romy,Santoro Antonio,Smirnova Ekaterina,Sorbara Simona,Tensi Leonardo,Tusha Gers
Abstract
The title two-dimensional coordination polymer, [Zn(C6H5PO3)]
n
, was synthesized serendipitously by reacting a tetraphosphonate cavitand Tiiii[C3H7, CH3, C6H5] and Zn(CH3COO)2·2H2O in a DMF/H2O mixture. The basic conditions of the reaction cleaved the phosphonate bridges at the upper rim of the cavitand, making them available for reaction with the zinc ions. The coordination polymer can be described as an inorganic layer in which zinc coordinates the oxygen atoms of the phosphonate groups in a distorted tetrahedral environment, while the phenyl groups, which are statistically disordered over two orientations, point up and down with respect to the layer. The layers interact through van der Waals interactions. The crystal studied was refined as a two-component twin.
Publisher
International Union of Crystallography (IUCr)
Subject
Rehabilitation,Physical Therapy, Sports Therapy and Rehabilitation,General Medicine
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