(2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3 N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)

Abstract

In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond.