Bis(dimethoxyethane-1κ2 O,O′)pentakis(1,1,1,3,3,3-hexafluoropropan-2-olato)-2κ3 O,3κ2 O-μ-hydroxido-1:3κ2 O3-oxido-1:2:3κ3 O-magnesiumdialuminium

Author:

Lozinšek MaticORCID,Pavčnik Tjaša,Bitenc JanORCID

Abstract

Partial hydrolysis of a sample of [Mg(dme)3][Al(hfip)4]2 crystals led to the formation of the title complex, [Mg(dme)2{HOAl(hfip)2OAl(hfip)3}] (dme = dimethoxyethane and hfipH = hexafluoroisopropanol) or [Mg(C4H10O2)2O(OH)Al2(C3HF6O)5]. The magnesium cation exhibits a distorted octahedral coordination with two bidentate dimethoxyethane molecules and a dinuclear aluminate anion, coordinated to Mg2+ via oxido and hydroxido units. The anion is an oxido-bridged species, [HOAl(hfip)2(μ-O)Al(hfip)3]2–, with one Al3+ cation tetrahedrally coordinated by an oxido (O2–) anion, a hydroxido anion, and two hfip groups, whereas the second Al3+ cation is coordinated by the oxido anion and three hfip groups.

Funder

European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme

Jožef Stefan Institute Director's Fund

Slovenian Research Agency

Publisher

International Union of Crystallography (IUCr)

Subject

Organic Chemistry,Inorganic Chemistry,Analytical Chemistry

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