(Z)-5-(4-Bromophenyl)-3-{[(3,5-dichlorophenyl)amino]methylidene}furan-2(3H)-one

Author:

Mayorova Oksana A.ORCID,Grinev Vyacheslav S.ORCID,Yegorova Alevtina Yu.ORCID

Abstract

The title compound, C17H10BrCl2NO2, crystallizes in the monoclinic space group C2/c with a large cell volume of 6207 (3) Å3. The asymmetric unit of the title compound investigated at 120 K contains two crystallographically independent molecules (Z′ = 2). Each molecule demonstrates slight non-planarity in the solid state and a Z-configuration for the exocyclic C=C bond. The crystal packing reveals the presence of π-π stacking interactions between the substituted benzene rings [centroid–centroid distances of 3.836 (5) Å, shift distances in the range 1.272–1.843 Å].

Funder

Russian Foundation for Basic Research

Publisher

International Union of Crystallography (IUCr)

Subject

Rehabilitation,Physical Therapy, Sports Therapy and Rehabilitation,General Medicine

Reference7 articles.

1. Bruker (2013). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.

2. Bruker (2014). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.

3. OLEX2: a complete structure solution, refinement and analysis program

4. Grinev, V. S., Osipov, A. K. & Yegorova, A. Y. (2018). IUCrData, 3, x181224.

5. Study of E/Z isomerization of (arylamino)methylidenefuran-2(3H )-ones by 1 H, 13 C, 15 N spectroscopy and DFT calculations in different solvents

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3